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Please check the General Settings for the SCS Email for location specific settings.
If you are setting up a new Outlook installation, it will automatically ask you for account information. Otherwise, navigate the menu to find the new account button:
Tools->Options->Mail Setup->Email Accounts->New
When Outlook connects to the SCS mail servers, you will see messages warning that the security certificate cannot be verified. When you see these messages while checking your SCS email, click Yes to continue using the SCS mail and imap servers.